Well, 'Talk Around' usually means simplex on the repeater OUTPUT frequency, but, otherwise, yes, it's an old 'trick' to use simplex on the repeater input (with no tone so the repeater doesn't repeat it) as a semi-secret channel.
The FBI used to use this a LOT at bank robberies, not so much for secrecy, as because the handheld units in the bank couldn't hit the repeater, so they'd use simplex on the input, the outside units could hear them (being nearby), and the outside units would still be repeated, so they could relay to base by just repeating the info themselves.
Of course, range to handheld/mobile units is rarely above 4-5 miles, unless you have a particularly high hill you're listening from.