It really depends on a number of things.
There could be two scenarios..
One, both scanners scanning, and two, both scanners paused on the same frequency. If they're both paused on the same frequency, then both of the scanners should recieve at the same time.
Now, in the next situation, we have both scanners scanning. The scanner with the most frequencies, would definately be at a disadvantage, because it would have to scan all the way back to the active frequency in order to recieve it. So If you've got one scanner with 5 frequencies, and another scanner with 1000, naturally, the scanner with 5 is going to "catch" the frequency first.
Hope this helps.