Might have been a finger slip while you typed the frequency but most 5Mhz band aeronautical HF frequencies are around 5.5xxMHz - the two tones (4 actually) are the 'selcal' tones.
The control centre will pick the most suitable frequencies for primary and secondary use, so the 5.5Mhz frequency probably is assigned as 'primary' in the evening, an 8 or 3 Mhz freq may be the secondary
Brandon beat me to it! He obviously has a better local knowledge!
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