Never heard of a system using two CC's at the same time. No known benefit and you're using a channel that could be used for voice.
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Not being a Certified Motorola P25 Trunk Systems Architect I can only take guess. My guess is, it might be useful as disaster recovery safeguard.
If you have two CC's running, the default or Primary CC will be handling the system. If the default Primary CC fails, the field radio's will automatically look for an active CC. Since it's already running the switch over time should be sub second. No human intervention required. No noticeable loss of functionality in human terms. I would expect the system Controller would see the change and send an alert of the Primary CC failure to whoever gets notified (system ops, Moto).
In the standard setup, you have one active CC and one or more standby AC's. Some mechanism has to recognize the CC failure and then notify the system controller of the CC failure. Then the controller has to activate one of the standby CC's. How long that process takes, I don't know (that's a Moto question), once it does happen then the radio's have to respond to the new CC. But my money is on the first setup with two active CC's as being a faster response.
Regarding your suggestion of a needless waste of an available voice channel. I feel that's a false assumption. The system in question has 1 CC and 3 AC's. You could use two of the AC's for voice in a pinch. But.... a good system manager would never put the system in jeopardy by using all three AC's, leaving no backup. In my opinion, that would be unacceptably poor systems management.
Since we are talking about a system that will play a large roll during the RNC. I would expect every entity involved to be going above and beyond the norm. So that's my best guess.