IMHO you are not going to find "Federal LE" having FPP or "freq savy agency" adding channels.
Most radios are locked down with the multiple zones per MOU's and/or Dept channel plans.
A Radio Tech maybe, but not a field agent.
I would think, based on my East Coast [and times of travel] that there are still plenty of shared Frequencies
to be discovered, and with the NTIA pushing more to conform to the input/output/simplex plans, what used to be
"Exclusive" to one agency in a wide area is No more.
Just like Part 90 agencies looking at RailRoad, Part 22 and NTIA channels, the RF fight for spectrum continues.
Heck two examples from my back yard:
172.9000 which we all would assume is TSA [former FAA] is assigned to also ICE [yes same parent agency]
and then also re-use within monitoring distance of similar NACs - OPB in Maine using #00, but ICE in VT/NH also
using the same frequency and similar NAC pattern. Only way to know is start also logging RIDs
And unless any of us have access to Spectrum XXI - we will never know as hobbyists - all/most are assumptions
And YMMV is my favorite part of Federal Monitoring - you never, ever really know what you will find.
I now return us to DVP/DES mode
Everything Bill said, and I wouldn't put it past some RF-savvy FBI agents to have other fed channels in some zones that they could strap for encryption and pop up on for a quick mission and then disappear. I don't see why it would be an issue as encryption defeats monitoring, but if they were worried about being detected in the first place of being nearby with Quick Call, SDR RID tracking etc, popping up on a fire tac, outside of season, would be a decent cover to provide security by obscurity to the bad actors.