"Having my scanner with me, I was wondering if having my scanner turned on while in one of these blasting zones would be considered "illegal".
Is a scanner a TWO way radio?
"...they didn't want a 2-way radio transmission to inadvertently set them off. Purely a guess, though."
If your guesses are that pure I wouldn't want you supervising a blasting operation.
"...the Army was using it when driveing through "hostile" areas to detonate any radio-controlled bombs before they were in the blast range."
I used to drive down a particular street setting off car alarms with my 2M transmitter keyed. Good thing it was Elizabeth and not Kabul.
"Mostly that caution comes from using electrical blasting caps."
Lindsay to the rescue! (Thanks for bailing me out of this mess.) These days multiple detonations are set off with a single cap and lots of primer cord. A single radio transmission strong enough or a nearby lightning strike at the wrong time can bring down the house, literally. BTW, I love that show where the Mythbusters vaporized a cement truck.
"Some units, such as Cellular phones, do not allow the user to control the transmissions, so they must be turned off in order to not transmit."
Don't kid yourself, cell phones are never off. You have to turn them "off" for them to be programmed by the central computer and they still transmit verification back. That's an example, the unit still has to transmit when polled to report it's status so the system knows IT'S status on the network. Beware of GPS equipped phones, you can be tracked. That's how a kidnapper was caught recently and his hostage found, the dope's unit ID was logged when he made the ransom demand and he left it at the hostage location. Spooky, isn't it?