The answer to your question is yes, but not exactly.
For me it is not just about CHP. And the list(s) doesn't end at the state line. In the "older" scanners such as PSR-310/PSR-500 that employ dynamic memory (lists), I organize my lists by county. As I cross a county line, I turn off the county I just left and enable the one ahead of me (the one I just entered is already on by this point). Organization of the lists include CHP (or equiv) for the county, plus the sheriff, fire and other channels.
I have a list I actually call I5 which is programmed to handle from San Joaquin Co, CA to King Co, WA. Because of limits (20 lists, 1800 objects) I have to be careful about what gets in there. I don't usually include fire tac channels or PD secondary channels. But I'll get to hear what's going on around me, focusing, but not limited to the freeway.
It's a new game with the SDS scanners because they'll hold the entire continent in them. 100 lists of 100 systems with 100 departments and endless channels under that. Presently Favorite Lists are state, System is either county or trunked system and so on.
Before a trip I haven't exactly taken before, I'll map out the expected highways, mileages where I expect to change counties and scanner codes needed when I cross those lines. These are just simple text files I prepare and print on paper.