For the frequencies check the database. In Maryland it's listed as 'Dept of State Police'. For the most part it's a 39 mhz system and simplex, meaning that it's not repeated over a wide area. You will need a pretty decent mobile antenna to hear them. I would always keep 155.73 (portables) and if I was in the Cecil county area, 151.04 (which is the SHA repeater - which serves as the translator for the 39.24 Barracks M freq) handy.
Not necessarily in any particular order, Barracks A, Q, P, F, M, R and D would cover the I95 corridor from the Delaware line to the DC line.
If I were in Montgomery or PG county I would also keep 39.62 handy, as that's the PMARS translator from 800 mhz 73s Mike