Import a system that has multiple sites into a scanlist.
After the import is done, go to the Trunked Radio Systems tab and click on the system your just imported.
Then, in the Site Details tab on the bottom left, lock out all but one site.
Then, click the Duplicate button on the top right.
Click on the new (duplicated) system at the top.
Then, in the Site Details tab on the bottom left, lock out all but one (different) site.
Then, go into the Talkgroup Details tab, click on any row and then Ctrl-A to highlight all rows.
Select a different scanlist on the right of the table.
Repeat as many times as necessary.
EDIT: Sorry - I may have misunderstood what you were trying to do -- what are you trying to do?