Locations/Freqs
The reason it can be helpful to know locations is that it can enable you to maintain a good receiving signal on the system. The other reason may be to hear the talkgroups you want. On a statewide smartzone/apco system, not all talkgroups will be on all towers all the time (typically), so knowing which frequencies relate to which tower locations helps you 1. hear the system at all, 2. possibly hear talkgroups in the area you want.
Real users of this system with their Moto. gear don't have this issue, since their radio scans a list of control channels picks one and logs on, voila, the channel they are on will be active on the tower site their radio logged onto. Of course as a scanner user you don't logon, but still need a means to get the right control channels into your radio. Their are many different ways to do this and I'm sure alot of posts about it here on RR.com.
In general though, whether I was using real moto gear or a scanner, I find the best reception has come from, deliberately selecting the right frequencies for the tower site I wanted to monitor. Often, more than one tower site will be monitorable at a given location (in many systems), but some will be closer to your location, and have stronger signals. If you set up a radio for control channel only mode be it scanner or Jedi series moto, it tends to logon to the first usable control channel it finds, not neccessarily the strongest or the most local. I used to cup my hands around my moto antenna to force it to return to scanning, and latch onto a stronger repeater site.