127.700
From doing a lot of listening while sitting at the airport, I think this is the way they have it set up:
Flights from other places are routed over 4 points inbound to Charlotte, From the Northeast is routed over a point just to the north of Salisbury, from the southeast or south (say Florida) is routed over Chesterfield VOR in SC, flights from the southwest are routed over a point southeast of Spartanburg and from the northwest is routed over a point southwest of Hickory.
For a flight inbound from the northeast, they are handed off from Atlanta Center to Charlotte Approach on 126.150 somewhere around Salisbury. The controller there will get the flight descended and generally lined up for the runway they will use. If the flight will land on either 18L/36R/23, they will be handed off to the final controller on 127.700 when they reach a certain point and altitude. That controller is mainly concerned with spacing and getting everyone lined up for the runway. When the flight is about 5 miles from touchdown, they will be handled off to the Tower on 118.100.
I think the way things work is that 126.150 handles flights over Salisbury and Chesterfield. 125.350 handles flights over Spartanburg and Hickory. As stated, 127.700 is the final for 18L/36R/23. 119.000 is the final controller for 18C/36C and 132.700 is the final for the new 18L/36R runway. The best I can tell, 128.325 is for places like Concord and Stanly County and also for low altitude flights to the east. There is probably an equivalent frequency to the west for Gastonia but I haven't ran that down yet.
Departures go out between the arrival routes, a flight to the northeast from Charlotte generally flies east of the city and climbs. When they get to a point between Charlotte and Albemarle, they are cleared to turn on-course.
Again, most of this comes from listening, I may have it wrong in some places since I don't live down there but maybe it might give some of you closer something to play with if you are interested. If you look at the CLT page on airnav.com, you see PDFs for the arrival and departure routes.