Yeah there is a bigger issue going on.
You cannot lock out a specific radio from being received by your scanner. No way, no how. If you monitor a given channel, you have to listen to every radio that transmits on the channel. Picking and choosing is not an option.
The radio system administrator should be able to deal with a situation where a microphone is repeatedly in transmit when it shouldn't be. This administrator should know exactly who is using the radio with the given Unit ID. (Of course the administrator should have set the time out timer too so this does not happen).
And as noted above, if a kind word to the radio user doesn't fix the problem the administrator has ways of dealing with it, as in kicking it off the system.
A codeplug is in essence the programming for the radio, such as frequencies, scanlists, systems etc. If it was a scanner, we'd call it a "Profile".