Here's a not-too-long-ago thread about Chesterfield SD indicating that they mostly use their UHF frequencies, with occasional use of Palmetto P25. So that would likely explain why you're not hearing much on the Palmetto P25 talkgroups.
I notice that the Chesterfield County license for 460.350, KON307, includes emission designations 7K60FXD and 7K60FXE. These are emission designations commonly used for DMR digital radio systems. This doesn't necessarily mean that they are running a DMR system, but it means they are properly licensed to do so.
If you're not hearing analog traffic on 460.350 and you're not hearing routine traffic on the Palmetto P25 talkgroups, I would recommend scanning 460.350 in "Search" mode to see if a digital mode is in use. How you do that varies from model to model.
Report back with what you figure out.