CFD uses only two frequencies to transmit the "voice alerts" to the halls. They both carry the same information but cover different parts of the city (and area surrounding).
418.4875 is the main channel broadcast from Rotary Park, near downtown. It covers most of the city.
413.4875 is broadcast from Spy Hill, in the far far northwest. It covers the north edge of the city (which is "shadowed" from the main site by Nose Hill, mainly) and areas outside like Springbank and Balzac.
The actual tones heard in the hall, as well as the method used to select which halls get to hear the alerts, are done over a wired connection from dispatch to each station. So that part isn't monitorable.
Most of the EMS "hospital patch" stuff these days is done over cell phones and/or landline phones. In the rare case that a crew needs to talk to the hospital via radio, EMS channels A6 thru A9 are used. They are in the RRDB trunking section marked "Calgary Digital Radio System".