YES, just put the frequency in question in a conventional scan list and select the audio type as "digital search", this will automatically display the P25 NAC being used. Keep in mind if the audio type is "digital" it won't allow you to hear any analog transmissions. If you're not sure if the frequency is analog or digital, select the audio type as "All" and you'll catch everything.
In Southern Colorado there is a National Park service frequency for the Sand Dunes National Park that operates in P-25 AND conventional mode on the same frequency. AFAIK, different users use the conventional side vs. the P-25 side, and they've been doing it this way for quite a few years. I really don't understand the logic for such a setup, I'm assuming some idiot at an administrative office thousands of miles away decided they didn't want to buy P-25 radios for all users.
I'm not sure how common this in other National Parks, I would hope most parks give everyone P-25 radios or just setup another P-25 repeater.