Ray's site shows several screen shots of the the CPS. I think that's enough to do the programming.
There is no single place or document that I know of the has all the info on programming the Pro Series. You've got to do a bunch of searching to gather the info. I've been prowling the net, batlabs, RR, and a couple of other forums for four years now learning about the Pro and Commercial series plus a couple of side trips on other Motorola radios. Everything I find gets digested, and in many cases, added to a pile of notes that I keep in a binder here.
If you are just doing station alerting without all the bells and whistles that Ray documents, you may have better luck using the Alarm function instead of the PA system. It just requires Pin #4 to be set to Alarm (Output). I think you set the active level HIGH which will power the relay briefly and trip whatever you are controlling.
We have a similar setup on our base, but it triggers a Zetron Model 19 which records the dispatcher's message and the blows our tones and plays the message. I will take a look at the programming and see how our shop set it up. It was an old system that they built in the '90's based on a GM300. When we purchased a new CDM1250 two years ago, we had them come back and move it over. They had some problems along the way and had to install a new trigger relay. Also, somewhere in the move, the alarm transistors got blown in the radio which necessitated another repair. Something to keep in mind.