I just listened to both.
42.44 MHz = Dispatch and Vehicles
45.10 Mhz = Vehicles
I then watched them both simultaneously on the waterfall and confirmed the above. Dispatch does not come through on 45.10. Also, the signal level is the same for vehicles on 45.10, so I figure they are being repeated.
I don't know what you mean by "the waterfall."
Also, the CHP does not have repeaters, they feed the mobile frequency audio through to the base frequency audio. They do most of this in urban areas and the large rural areas don't have this feature. That is because units are more spread out both in distance and topography, with units being able to only hear one, maybe two, remote base stations at the same time. This mobile to base patch would not be heard by the majority of units so there is not an advantage, except for the units currently working that one site. In addition remote base station receivers use a voting system and a unit might be going between sites intermittently in the same transmission or a series of transmissions.
In addition, since vehicles use both the mobile and base frequencies (car and station in CHP lingo) with the mobile frequency transmitted to remote base stations and car to car communications being on the base frequency, you often can't hear the mobile frequency at all, as it can be buried in terrain while the remote base is on top of a peak transmitting at 4-5 times the power. In rural areas not using the mobile frequency to base frequency patch you only hear units transmitting on the base frequency if they are close or topography/distance allows.
Strange, I wonder what the purpose is. Are the mobiles still on 42.76 and/or did you see any other inputs?
Presumably, the 45.10 base should have a mobile of 42.620 as you mentioned. The database does not show a Pink 2 mobile for Porterville/Visalia. The only other Pink 2 in the RR database shows a different base frequency, this for West L.A. in the Southern Division. I could probably dig back in my written material and find the 45.100/42.620 pairing though. The pairing shown in the database, 42.440/42.760 should be current. Have you heard any mobiles on 42.760? I guess not as otherwise you would not have posed the question you have in your second post. Transmitting on both Pink and Pink 2 at the same time would seem to indicate that the area offices are in the midst of a transition. However, I haven't followed these area offices closely, so I don't know how long this transition has been the case. I wonder if in this transitional period they are using 42.76 as the mobile for both?
If no one else on RR knows the answers, my suggestion would be to drive to one of their remote base mountain top sites, then listen as mobiles transmit to dispatch and see if both the Pink and Pink 2 base frequencies have the same reply transmissions. It would require at least two scanners and decent antennas. It is surprising how well you can hear the mobiles from on of the CHP remote bases. I just saw your location is Marin County, so this suggestion might not be very easy.