Share please, always share. Others may be having the same issue. Even if you feel it was a beginner's error, or something dumb, I can guarentee that others will be there at some point, so please share the solution. Thanks.
Well, The problem started. When I found out, my BCD325p2 did not have an LCN Finder. Despite being able to upgrade it with DMR n' NXDN to the scanner.
So, I had to attempt LCN via the third-party software DSDPlus, and SDRSharp. The software didn't list my scanner correctly.
Instead of my scanner, the BCD325p2(Handheld) being listed. It listed the BCD996p2(Base). Which I don't own. So, Thinking my printer having been listed. That my printer would now be blocked, I changed a setting to the BCD996p2. Now, Proscan will not connect to my scanner. The 996p2 is still listed in the Device Manager under USB Devices.

So, I have to somehow, change it to its' previous setting of my printer.