I added some explanations of Charleston County fire and EMS talkgroups at the top of their respective talkgroup groups on the RR database page for Palmetto 800. Based on my little bit of listening, Ops A and B are more used for admin communications. Fire units are assigned an Incident channel as part of their dispatch for response/ops communications. The most commonly used Incident channel for fire responses is Incident 4.
Your description is helpful and clears up some questions I had based on listening during my travels to Charleston.
One remaining question - how is the Charleston City talkgroup that is labeled "FD Ch.1 Ops" actually used? Are there actual operations on that talkgroup or, as suggested by the explanation you added to the Charleston County Fire Departments group, are operations always on an Incident channel?
I leave this to you and other local experts, but it may be helpful to add an explanatory note in the text field for the Charleston City talkgroup group, since someone looking specifically to monitor Charleston FD (or just learn about how they use radio channels) wouldn't necessarily see the description in the Charleston County section.