As with other times I have tried to research this; it isn't appearing to me that there is a significant daily difference between day and evening and GMRS propagation. Perhaps it is simply an elevated RF noise floor in the daytime?
VHF/UHF & Free Space propagation
"- 2m band – This band falls in the middle of the VHF spectrum and is ideally suited for frequent DX using almost all the modes available to the 6m band plus the manifestation of trans-equatorial propagation mode across the equator that might cover DX distances in the order of 6000-8000 Km.
- 70cm band – Most of the propagation methods cited above are also applicable to this band, however, the probability of robust and reliable Sporadic-E as well as Trans-equatorial openings get significantly reduced due to the lack of sufficient ionization density required at these frequencies. On the other hand, the tropospheric scatter mode becomes more frequently available due to the reduction in wavelength."
70cm is what we are looking at so for day/night propagation influences, I looked at the VHF entry below...
Atmospheric impact on VHF Radio Propagation