Hi Saddletramp,
Glad to hear you want to become a ham. You've received some good advice so far, all that I will add is that while you are studying and asking questions towards passing the exam (if I can do it, anyone can!) try tuning your scanner to the VHF and UHF amateur bands and listen in, just to see who's out there and what's going on. Tune between 144.000-148.000mHz for VHF and 440-450mHz for UHF. Your scanner may even have the ham bands preprogrammed in the Service Search mode.
After listening for awhile, you'll begin to become familiar with how hams operate and the lingo used, which is quite different than CB. Listening like that will make things much easier when you make your first contact. If you tune in almost any weeknight between 7:00PM-9:00PM, you'll probably hear some "nets" in progress. They usually start on the hour and half-hour and last for about a half hour or so.
As has been suggested, find a local ham club in your area and go to a meeting. Surely you will be welcomed and mentored towards taking the test. Then, when you get on the air for the first time, you will have some friends already to "ragchew" with.
In addition to the ham pages here in Radio Reference, try also the ARRL, the American Radio Relay League:
American Radio Relay League | ARRL - The national association for AMATEUR RADIO
Lots of good stuff there to get you started.
Again, welcome to amateur radio!
Regards,
Jim KC2LMH