Yes, you can go down the rabbit hole of trunked system logging and use the affiliation data collected to figure out if a talkgroup is restricted to specific sites. It is different from listening to the system as your listen to the control channel and collect the data being transmitted.
How it works is that every radio on a trunked radio system needs to
affiliate to a talkgroup on the site it is trying to use before it can transmit or receive. When a radio tries to do this with a site, the site will let the radio know if it is successful or if it has been denied. Being denied affiliation is a sign that the specific talkgroup that the radio is trying to use is not allowed on that specific site and the radio is then forced to try to affiliate to a different site.
For P25 systems, I personally prefer
Pro96Com if you have a supported scanner as it has the most intuitive UI out of the different programs out there. There are a bunch of others programs out there that are listed on the
Trunked Radio Decoders page, many of which work best if you use a software defined radio (SDR).
There is an entire
Voice/Control Channel Decoding Software forum dedicated to monitoring radio systems this way.