While lots of people use marine frequencies for things other than there intended (or legal) use, that's probably not the case here. The turnpike uses properly licensed VHF high frequencies in their maintenance vehicles. In your case, you were in very close proximity to both the vehicles, and the output of a repeater located on the top of the mountain above the Allegheny tunnel. My guess is that the radio you were using has a pretty wide front end and given the power and close proximity it just bled over onto the frequency for channel 14. The listed frequency for channel 14 is 156.700 and the output of the repeater for district 2 right above you is 156.225. Also possible is depending how good/poor the filtering in your radio is that you were getting chatter from their mobile to mobile channel at 159.000.