Ever since Metrolinx took over dispatching duties for track they own, they've been eager to also get off CN's radio channels. Part of this is about ownership, but the other part is practical: there's an awful lot of interference on the CN 01 standby channel, especially north of the city. This is why the Uxbridge and Weston subs changed to using CN 42 (AAR 089, 161.445) as a standby instead of CN 01.
I'm not sure what the RadioReference policy is on this, but I don't think it's a "system" per se: it's just replacing the existing CN conventional simplex railway channels with Metrolinx's own simplex railway channels, some of which are NXDN. It's not a trunking system. I think RR is also missing CN 42, and the TTR analog channels in the USRC. But my interaction with the RR database is limited mostly to Uniden Sentinel, so maybe I'm just not finding where it's organized (e.g. by subdivision or rail operator). If I could see it I'd suggest specific changes.
Anyway...
Right now, the digital radio migration project affects the GO-owned portion of the Kingston and Bala Subs and the Uxbridge Sub. However, not all equipment has moved over yet: for example, there were issues during testing with some of the DTMF-triggered level crossing controllers that remain analog for the time being.
Here's what I've figured out so far (all NXDN4800 RAN 0):
Bala Sub (0.0-16.1)
Standby: (?) (GO 3 would fit the pattern but I haven't heard anything to confirm)
RTC (Metrolinx Toronto North): GO 4 / AAR 377-377 160.740
Uxbridge Sub (38.9-61.0)
Standby: GO 5 / AAR 337-337 160.440 (there are signs for this at Scarborough)
RTC (Metrolinx Toronto East): GO 6 / AAR 401-401 160.920
Kingston Sub (313.9-333.8)
Standby: GO 7 / AAR 321-321 160.320 (there are signs for this at Cherry St and Scarborough)
RTC (Metrolinx Toronto East): GO 8 / AAR 389-389 160.830