The City of Maricopa Fire Department is dispatched by the Phoenix Fire Department Regional Dispatch Center.
You want Simulcast C of the Regional Wireless Cooperative trunked system for the K-deck EMS talkgroups, and you will also want the VHF-High A-deck frequencies for fire and HazMat calls.
K-1 on the RWC and A-1 on VHF-High are multicasted dispatch channels. You won't be able to single out just dispatches for Maricopa FD units until you develop a practiced ear. You'll have to listen to every dispatch for the whole PFDRDC until then.
I believe K-8 is the usual EMS Tac talkgroup Maricopa units are assigned to, although there probably won't be much in the way of voice traffic on most calls, since much of it is a button press on the MCT in the rigs. Large incidents may be put on K-10 through K-12. I think A-8 is the usual fireground channel assigned in Maricopa.
The RWC:
Regional Wireless Cooperative (RWC) Trunking System Profile
www.radioreference.com
Scroll down to Phoenix for the VHF-High channels:
Scanner Frequencies and Radio Frequency Reference for Maricopa County, Arizona (AZ)
www.radioreference.com
John
Peoria