I don't have a second charger; I have 2300mAH NiMH batteries in mine. NiMH battery manufacturers claim that NiMH doesn't suffer from "memory effect" as much as NiCd, so don't have to be fully discharged before recharging them. If those claims were true, there would have been no reason for companies to start making Lithium-Ion batteries. My experience is like others on this board, that they don't tend to last as long if you "shallow-discharge" and recharge them often.
The PRO-95 is designed to be able to charge NiCd or NiMH batteries, which is stated in the manual. However, the charging circuit is very simple and it WILL overjuice the batteries after they reach full charge. If this is the only charge method you plan to use, it's important to keep a mental note of how discharged the batteries are, and likewise, how long you leave it on charge. The formula is basically 1 hour per hundred mAH rating. Keep in mind that the radio will not run the batteries to "zero" charge, either. It will shut down when the batteries drop below the operating voltage, so 2300mAH batteries probably only need about 18-20 hours to reach full-charge again.
Someday I'll just do the smart thing and get a "smart" external charger, like others on this thread suggest.