In a word no - I derived your location from your posting and I am assuming that you want to monitor specifically the Ontario Provincial Police. They use a Motorola T2 trunked system with both analog and APCO-25 signals. Assuming again the model number of the scanner you asked about is correct - it is a analog non-trunking model from 1999. My suggestion is to save your money and get a more modern digital trunking scanner or at the very least an analog scanner that will do trunking.
Dennis