MDC can transmit the characters 0 thru 9 and the letters A, B, C, D or E. It actually uses hex numbers from 0001 thru DEEE, which allows up to 57070 different ID's. I don't know why the letter "F" is not allowed.
Some manufacturers of MDC decoders allow you to create a Call List that allows an alias to be displayed instead of the actual ID transmitted. For example the number 0410 would be transmitted but the display could read "Sgt. Smith" instead.
Therea re several ways a scannist can decode MDC. The WinMDC program already noted would work, as would outboard decoders. Cimarron makes a line of decoders that work well with record level or discriminator audio. I also occasionally see at hamfests or eBay various Motorola desk sets that decode MDC.
My agency's network uses 3 digit numbers for star numbers and each officer has an assigned portable, so they ID with his or her star number (0410, 0592 etc.). Mobiles have the letter "C" in the first position, to ID it as a car. Therefore my portable shows up as 0410, my car as C410. Since, as the local radio guy, I have more than 1 portable, I have other radios that ID as 410A, 410B etc.
Our local Fire dispatch center uses a different system. Rigs ID with the first 2 characters as the station assigned, the third as the type unit (xx1x are engines, xx2x are ambulances etc.) and the last character id's which radio on the rig. 2110 is the main radio from Engine 21, 2111 is the rear radio, 2112, 2113, 2114 are portables from the same engine.
If you can decode MDC it only takes a short while to figure out the numbering system.
Some repeater systems have a delay that keeps the MDC from being retransmitted most of the time. I have that "feature" disabled on my repeaters so that my mobiles and portables can decode the MDC (and I can watch it from home when I am really bored!).
When we rebuilt our system and replaced our old GE Mastr2 repeaters (with GE-Star) with Motorola Quantars a couple years ago the guys complained for a couple days about the MDC squawks, but eventually got so used to it that they do not even notice it any more.
Some systems also are set up to deny access unless a valid MDC code is transmitted.
GE-Star is another popular format. I happen to have an old GE-Star decoder that I occasionally set up. I recovered it from a console that I deconstructed a few years back.