All I can suggest - since most of the sticks we're using are susceptible to severe distortion and front-end overload with very strong signals - is decrease the gain considerably when you're monitoring that system. It only takes a few seconds to open the Configure menu and alter the RF gain down, and obviously for such a powerful signal there's zero need for RTL AGC or Tuner AGC (I stopped using either of those a long time ago). I have a few signals in the 460 MHz range that even with the RF gain set to 3.7 dB it'll still peak the spectrum at -10 dB because I'm like 4 blocks from the transmitter LoS, I can see the actual antenna from my balcony.
Let's just say the RF gain on my SDR apps gets altered quite frequently.
The other aspect with NXDN traffic - depending on the way they are set up, of course - is that they can be tough to nail down in terms of the exact frequency because of them being capable of that offset operation: every NXDN system here in my area that I've been able to snag recently is offset. The FCC license will show the primary frequencies but they end up transmitting either -3.125 kHz or + 3.125 kHz off that frequency, sometimes both at the same time. Can be either 2.5 kHz, 3.125 kHz, 6.25 kHz, or even 7.5 kHz off depending on the frequency bands, so if you note that you almost get them but not quite, the system you're trying to monitor could be offset on the transmitting side of things.
That picture you posted shows the peak being just slightly off the tuned frequency, might consider checking your ppm up or down 1 notch to get it centered on the peak - it might help, it might not, but in my experience with NXDN more so than any other of the digital protocols, it's extremely sensitive to the ppm and can result in horrid decodes if it's off by even just 1 ppm.
Might consider altering the FFT range too considering your noise floor seems to be at the "standard" of about -60 dB on average - anything below that level is basically not going to be seen (maybe on the waterfall I suppose but even so it won't show a signal peak on the spectrum) and you're making SDR# use more CPU power than necessary aka operate inefficiently by showing "nothing" on the spectrum all the way down to -130 dB.
Just my advice, of course...