Not really. It will always stay at least 1,5 sec on a control channel or higher if you set the hold time to 2 sec or higher. If it doesn't detect any conversations it will go to the next site in the system and again wait 1,5 sec and continue to all sites until it finds a conversation or run out of sites.
If it finds a conversation it will track and monitor it and when it ends it will exit from the system even if there are more sites in it. In its next scan cycle it will go directly to the last active site that had a conversation. To speed up scan, and possible miss some conversations, you can set avoid to all sites but the most active ones.
If sites are outside of your receive coverage they will be skipped in a few milliseconds if it can't detect any signal. I would think that for less important systems to you only use one site to scan but for the important ones you leave all the sites that you can hear in scan. For simulcast systems they will transmit all conversations on all sites so in that case you only need to scan one single site, the one with the best signal strength.
Sentinel can only import Unidens hpe files, so you will have to use some sort of program to convert to that format if you have a list of frequencies and TG's that you have found. ProScan and ARC have import functions that can handle different formats of data. If you use Excel you can enter your data and export to a csv format and ProSan and ARC can then use that data to program Uniden scanners.
From Excel you can usually simply mark a column of cells with frequencies and copy and then paste into Sentinels first line and it will automatically expand to the lines needed. The some goes for TG's.
If you have other scanners, like Whistlers, Icoms and AOR, you can also use that csv format from Excel. Some people only use Excel as their master database that they edit and then export from that to different scanner programs so they don't have to edit the same thing several times in different programs.
The site are still there and can create files formatted for Uniden and Whistler scanners:
Digital Frequency Search
/Ubbe