Keep in mind PROVOICE is not "Secure"
Unless it is known that the agency is using encryption on top of being PROVOICE then they're most likely just PROVOICE. Provoice is simply just another form of transmission. It's not secure in nature though. The reason why we "scanning hobbiest" can't listen to provoice is because the developer of provoice refuses to release the technology to scanner manufactures. Therefore we don't have a scanner capable of decoding the provoice digital signal, like we have with the motorola astro digital signal.
Jimsokol might be correct though. My county's public safety is using EDACS PROVOICE but at least one of the police departments on it has analog talkgroups as well and I have heard dispatch calls on those analog talkgroups. Unfortunately it was only during new year's eve. But the ability for them to simulcast their digital comms onto an analog talkgroup is possible (if they so choose to do so).