"Watt-hours" is exactly that - figure it to be the number of watts the battery will deliver for one hour. So, 320W-h means 320W for one hour.
Now, you can play with that - any combination that multiplies out to 320 will work. So, 80W x 4 hours, for instance. Or 20W for 16 hours.
Bear in mind that listed power on a radio is transmit power, not power draw. This means that your 10W radio will put out a 10W PEP signal, but it will consume slightly more 'leccy generating it and pushing it out - I'd not be surprised if your consumption figure weren't closer to 13-14W. So, figure 16W (to make the maths come out even,) for 20 hours. 16W x 20h = 320 W-h. YMMV, TANSTAAFL. Bear in mind that there are inversion and conversion losses, for instance, so you're not going to get the full 320 W-h. But, since you're not drawing the full 16W you're using to figure your battery longevity, that's essentially a non-issue, you can probably still count on 20h runtime. Longer, with the solar panel - unless it gives you a good 20-30W charge current, it will at least slow down the draw loss by partially replacing what you're taking (keeping the maths simple, say you've got a 10W panel. You're drawing 16W from your radio. 16 W - 10 W = 6 W, so that's what you're drawing from the battery. Or, since batteries themselves are rated in Ampere-hours, let us apply Watt's law, and 6 W / 12 VDC = 0.5 ADC. If you can somehow make up that half-Ampere of charge, you can keep your battery static. Perhaps a wind turbine? A water wheel, if you've got a stream handy? Be creative!)
Ohm's Law: E = I x R. E = Volts [V] (Electromotive force.) I = current [A] (I don't know why.) R = Resistance [ohms]. "AC" or "DC" is usually specified, as in "VAC" or "ADC." Resistance doesn't care.
Watt's Law: P = E x I. P = Power [W] (Watts. Doesn't care what sort of current.) E = Volts [V] (Electromotive Force.) I = Current [A] (Again, I don't know why they use "I" for this.)
These two are often combined as: P = [I x R] x I, or P = I^2 x R. Engineers use this combined form a lot when figuring transmission lines (when they're figuring "I-squared-R" losses.)
If you're going to get into any sort of electronics, or bone for your ham ticket, tattoo those two formulae on the inside of your eyelids. As they told us in training: "Gentlemen, you will see this material again." (This was your cue to write. It. Down. If I say that, find a notebook.)