Thanks for running this down freqhopping. It was very helpful to have a second set of eyes from another point on the ground. So my best guess on 462.0 is Arlington, one of the FCC licenses WPPY565 (Commercial Communications Inc.) actually turns up on a fairly nearby transmitter. According to the license info, this station has four emission types on it, listed out below. Of these, the 462 MHz signal seems more consistent (at least to my amateur eyes) with a 7.6kHz bandwidth, and since I don't think its voice, my best guess (again, amateur/idiot here) is 7K60FXD 2-slot DMR (Motorola MOTOTRBO) TDMA data. DSD not helping. Still not sure about the 453.950 signal, but now that you mention AVL, I have seen similar looking UHF signals associated with WMATA's AVL system. Thanks again, let me know if you ever need me to check out a signal from here to return the favor.
11K2F2D--
Bandwidth: 11.2 kHz
Modulation Type: [F] Angle-modulated, straight FM
Modulation Nature: [2] Digital, with modulation
Information Type: [D] Data, telemetry, telecommand
Modulation Type Notes: F2D Data transmission by frequency modulation of a radio frequency carrier with an audio frequency FSK subcarrier. Often called AFSK/FM.
Emissions Designator Notes: 11K2F2D Audio frequency shift keying within a 12.5 kHz channelspace (commonly used for 1.2 kbps packet, FFSK station alerting, and AFSK tornado siren signaling)
11K2F3E--
Bandwidth: 11.2 kHz
Modulation Type: [F] Angle-modulated, straight FM
Modulation Nature: [3] Single analog channel
Information Type: [E] Telephony, voice, sound broadcasting
Modulation Type Notes: F3E FM speech communication – often used for marine radio and many other VHF communications
7K60FXD--
Bandwidth: 7.60 kHz
Modulation Type: [F] Angle-modulated, straight FM
Modulation Nature: [X] Unknown
Information Type: [D] Data, telemetry, telecommand
Emissions Designator Notes: 7K60FXD 2-slot DMR (Motorola MOTOTRBO) TDMA data
7K60FXE--
Bandwidth: 7.60 kHz
Modulation Type: [F] Angle-modulated, straight FM
Modulation Nature: [X] Unknown
Information Type: [E] Telephony, voice, sound broadcasting
Emissions Designator Notes: 7K60FXE 2-slot DMR (Motorola MOTOTRBO) TDMA voice