APCO maintains (or did as of last year) a list of which public safety agency is actively using which VHF-Low channel. I'm not sure how complete or accurate it is, but I thought it was useful to compare who was still using low band versus who just kept renewing the license.
After a storm, I sometimes hear out-of-town power companies helping with repairs on the itinerants.
Every once in a while, I hear casual chit-chat on one of the low-power business frequencies. It doesn't sound like a business, but it's so infrequent, I guess propagation has to be just right.
Other than public safety users with unit numbers, I never hear any IDs from anyone.