5 amps isn't enough to power a 45 watt UHF radio. 10 watts is going to be a little light, also. The power supply is going to be working pretty hard at high power.
That channel may be impacted for a couple of reasons:
Higher SWR when transmitting at 467MHz could be reflecting power back to the radio and causing it.
The radio may not be as efficient on the higher transmit frequencies.
Usually, when aligning a radio, the power levels are set at various places along the spectrum where the radio will work. It might be slightly high around 467MHz. Adding a higher capacity power supply will address it.
If it's a used radio, someone may have monkeyed with the alignment settings, or they may have adjusted the high/medium/low RF power set points.
A DC ammeter would tell you how much current the radio is drawing.
An SWR meter would tell you if the SWR is too high.
Another thing I'll point out…
You have some of the GMRS interstitial channels programmed in at high power. That's outside what the GMRS license allows. Those should be set to run no more than 5 watts. From the factory, the radio is set to TX at 10 watts on low.
You've got all your channels set to narrow bandwidth. That's fine if that's what you want, but under GMRS rules, you can run the primary channels (462.xxx0 simplex and 467.xxx0 repeater inputs) at wide.
Other than that, looks good. Should be a good set up for your mobile if you have a good antenna. Make sure you run your power for the radio directly to the battery, too.