I assume you're trying to build a repeater, correct?
What you probably have there is a simple bandpass filter, which passes the high frequency on the high side of the duplexer and passes the low frequency on the low side. They tend to be somewhat more reliable in mobile applications than BpBr (bandpass/band reject) duplexers which have more fiddly bits and are trickier to tune.... and Bp duplexers are cheaper. They also tend to be less reliable at higher power levels. Don't try to pump too much power through that thing, though; the more power you put in will cause higher desense on the receive side; you could even toast the duplexer or your transmitter, or both. Most of those surplus mobile duplexers are rated around 50 watts, but I would never put more than 25-30 watts into one.
In any case, it's just like zz0468 said; connect the high frequency side of your system to 'high' and the low side to 'low'. Be sure to use good quality low-loss (preferably double-shielded) cables between the transmitter, receiver and duplexer. If the duplexer has SO239 connectors, use the best PL259 plugs you can find (preferably silver plated with gold center connectors and teflon dielectric) and make sure they stay nice and tight. Also, your connecting cables really should be an electrical 1/4 wavelength at the frequency of operation.
Here's a really good tutorial on duplexers:
Duplexers: Theory and Tune Up
That all being said, those surplus mobile duplexers make dandy portable repeaters; I put one together for emergency use using a couple of Motorola Radius transceivers, a simple controller, and one of those mobile duplexers. Worked like a charm.