You can't. The FCC license info will tell you why types of emissions are allowed - but it won't tell you what specific trunking format was used.
If you've found something that isn't listed in the RR DB and you're in reception range - turn on your radio and listen. If your radio understands P25 ... you've got your answer. If you have an analog-only radio - there are sound recording samples of what the voice and control channel sound like on an analog receiver.