CB used to be an amateur radio band, if I recall. So there never was a type-accepted radio for that band, since there's no such thing as a type-accepted amateur radio. Amateur radios are only approved by FCC Part 15, which is the same thing that covers all electronic devices that use radio frequencies: the transmitter may not cause harmful interference. Once CB became the user of that band, all the ARS license holders had to stop transmitting there.
It's illegal to transmit with a modified CB, even if you're not transmitting out of band. The instant you make any repair or modification to a CB radio (or ANY type-accepted radio), that radio has to be serviced by a certified technician who can certify that it's still compliant.
You CAN transmit with a CB radio IN the 10 meter band if you hold an amateur license, but once modified to transmit 10-meters, that radio is not legal to use on the Citizen's band ever again.
MURS and FRS are also unlicensed services, similar to Citizen's Band. They also have the same restrictions: you may only use a type-accepted radio, and the radios have power and antenna restrictions.
You cannot use a commercial radio transmit on any frequency you don't have a license for. You may NOT program a Motorola land-mobile radio to run on GMRS, FRS, or MURS. You can't use a modified radio
anywhere, unless you're a ham using it on the amateur band.
The short version is that if you don't have a call sign, you should never open up the case on your transmitter, even to repair it. The instant you do, you break your type-acceptance. If you DO have a call sign, you should already know the rules you have to comply with.
And no, the cops aren't going to bust down your door for fooling with your CB unless you tick someone off: either causing a lot of RFI in the neighborhood or screwing with a license holder (I think the military uses < 27 Mhz, and the 29-50 Mhz band is used by a variety of services.) I HAVE talked to people who have been interrogated by the police regarding CB radios. One was a licensed ham who was harassed by an ignorant cop because the neighbors were complaining about RFI. The other had a "good buddy" who was sitting in his front yard, talking below 1 with a 1000 watt linear. BAD juju!!
There are also hams who jealously guard their airwaves; If you're frequently interfering with them, and you're in a fixed location, they'll gladly track you down and turn you in.