I'm not sure where you are in relation to Gonzales but I'm going to offer a few sugesstions.
Store the GPD/GCSO frequencies without any tone info (NAC for P25, CT/DCS for analog). That way, if they're using the frequency with more than one tone you'll hear it. This will open your scanner up to receive anyone on that frequency (so you might hear stuff from surrounding counties, though most stuff is coordinated better than that). For instance if GPD has 155.5875 NAC 351 for dispatch they could use 155.5875 NAC 352 (or any random number) for a "car-to-car" channel. Or they might use the input (or output) in low power simplex. Either way I leave my tones in "search" mode.
Also, try to listen to the "Caldwell County" site in the GATRRS (Austin/Travis County) system. The site appears to be near the Buc-ees in Luling. It's probably close enough to you to hear the traffic on that (not's that it's a bumpin' club either), but at least it's a P25 TRS for you. I identified a bunch of Caldwell County talkgroups in this sites infancy but haven't been monitoring it in a few months.
If you're that bored you can listen to GCSO (that's Guadalupe in this case...). Their Channel 3 reaches quite a ways and that's where you'll hear their K9s and Texas DPS for Guadalupe County.
There are also 2 LCRA EDACS sites in Gonzales County (Gonzales and Kingsbury). It looks like the Gonzales site has 3 LCNs (and maybe more if you could find them). If you set a group wildcard for these sites you'll start getting all the used talkgroups from them (if you set a private wildcard you'd hear any I-Calls or individual calls). Set each up as an EDACS Std trunked system and put the LCNs in order. Then manually select the TSYS and "analyze" it. By scrolling through the LCNs (up/down arrows) you'll find the control channel. It wil be a nasty sounding buzz, but if you look at your screen it will give you a signal strength (in %, as well as the S-Meter). You'd want about 80% or higher for good listening.
Sorry about the length, just know there is tons to listen to...