The answer for monitoring PG Police is no. Although most of the talkgroups are NOT encrypted, they are operating in the TDMA (Time Division Multiple Access) mode, which presently no manufactured scanner can decipher.
There are a few instances where a Prince George's County Police unit will communicate with another jurisdiction which uses FDMA trunking radios, and when that happens, you could theoretically pickup the transmission on a digital trunking scanner, but those times are so rare that it would not be worth the effort.
Prince George's County Fire units have not switched over to the new TDMA 700 MHz trunking system yet, but will do so next year. When they do, the same rules will apply, although they communicate with outside agencies more often than the police units so the chances of hearing them on a digital trunking scanner will be greater.
On the other hand, once the FD does switch over to the new system, they will simulcast their main dispatch channel on a VHF frequency (possibly 155.685, but that is not confirmed yet) for the benefit of the volunteer firefighters, so you could always listen to the fire dispatch calls on that frequency.
As far as monitoring police transmissions however, you are pretty much S.O.L. with a scanner.