When the ML414RU battery stops working on my 536HP I was planning on replacing it with a more common CR2016 battery and external holder/socket that could be mounted in a variety of locations inside the scanner with double sided tape. From what I've read both batteries are 3 volt lithium's and the ML414RU has a capacity of 1.0 MaH where the CR2016 when charged is 90 MaH. The even more popular CR2032, 3 volt battery is rated at 220-240 MaH.
Other than the replacement CR2016 having more capacity available has anyone already done this mod and does anyone see a problem with it?
Thanks for the original post and great pictures!
73, Gary
The common CR2016 or 2032 lithium cells are not intended to be charged period.
I'm not sure the 4 or 536HP models could provide enough charge current into the non rechargeable lithium cells is a question that I don't know the answer for but I would not advise charging either type cell even if the charge current is very low in the microamp range.
The LiR2032 is sold as a rechargeable cell and would work and should be safe but I sure would not attempt using the common CR/BR2016 or 2032's in a circuit that will supply charge current. When I added a similar sized (as Uniden's) rechargeable lithium cell into my 536HP in parallel with the OEM cell, the charge current was very low and well below the manufacturers specs for charging current. Uniden's charging circuit already supplied a max allowed voltage below the max voltage specs for those that sold rechargeable lithium cells so that also was not a concern.
When I did my mod by adding another cell in parallel with Uniden's cell, there were not many manufacturers that even sold rechargeable Lithium coin cells. The LiR-2032 was unheard of and about all that was out there were cells with about the same specs as what Uniden used.
The only equipment I knew of that used them were Motorola Advisor series pagers back in those days.
The rechargeable Lithium cells sold today use a different chemistry than your off the shelf non-rechargeable Lithium cells use.
Of course large items like laptop computers use rechargeable Lithium battery packs but those battery packs also contain very specialized charge monitoring and controlling circuits and most importantly, safeguards should something fail. Some even have safeguards for the safeguards but they do not always work as has been proven with laptop battery explosions.
Charging Lithium cells in not like charging NiMH cells but the technology is getting better. Even NiMH cells require proper charging circuits to be correctly charged.
Without those special circuits which usually monitor each individual cell, problems do occur as has been proven over and over by users whose expensive radios have melted down into an unrecognizable pile of melted plastic. Hence the reason that many do not recommend charging NiMH cells in the radio.
Read up on charging a normal non rechargeable lithium cell and you will find the warnings. Many of them.
Explosion of the cell is likely the number one reason against doing such.
On the other hand, many of the 35+ year old Icom rigs used a standard 2016 or 2032 and the original non-rechargeable lithium cells are still going strong today in many of those old Icom rigs like the R7000, R71A etc as well as the related HF transceivers.
Lithium cells generally carry a 5 to 7 year lifetime but the fact that many are still going strong even after 35+ years is thought to be simply because of the small amount of leakage current that will flow backwards through the very diode that prevents the cells from being charged.
If you take an old Icom rig that has sat in a closet for all these years, chances are that your lithium cell has long ago died.
It's the Icom rigs that have spent the last 35+ years plugged in with the memory circuit being powered where you will find the 35+ year old Lithium cells still maintaining a charge.
I think that's an unproven fact but it is indeed true. I own some that still have the original cells made in the 70's.
The leakage current through the diode that prevents the cell from charging is so small that is did not harm the cell and cause any damage.
I'm sure somewhere out there, someone has an old Icom rig that had damage from the cell being slowly charged all these years but I can't recall ever reading any stories about damage from reverse current leakage in the old Icom rigs.
Unless specifically made to be recharged, a lithium cell should never be charged.
If you do use a CR2032 or 2016 in a socket, I'd expect a pretty long time before the cells voltage goes low enough to no longer maintain the RTC. That would be due to the high cell capacity compared to the small cells Uniden chose but I'd install a diode in the circuit that prevents charging unless you are using one of the newer LiR 2032 rechargeable Lithium cells capability.
I still do not know if the 536HP even has the charge capacity to fully charge an LiR-2032 but someone did say leaving the 536HP turned on can and charging for something like 160+ hours would be sufficient to fully charge an LiR2032 cell.
I forget who said that and if that time was just an estimate or guess or based on actual tests with test equipment.
Use an LiR2032 instead as they are intended to be charged.
I doubt either model Uniden would ever exceed the LiR's max allowed charge current. The tiny cells Uniden uses in the x36 models are supplied by a very tiny amount of charging current which is why the long charging times already exist.
Just plopping a 2016 or 2032 into the circuit is a bad idea though as you are charging a lithium cell not intended to be recharged.
Not much different than charging an alkaline cell which will either rupture and leak eventually but charging a non-rechargeable Lithium is even more dangerous as you now risk explosion on top of any harmful leaking chemicals.
Both of which can ruin your expensive radio and also possibly cause a fire or bodily injury should it explode into your eyes for example.
So to answer your question, yes, there are reasons (several) for not recharging a CR or BR2016 or 2032 and other variations of non-rechargeable lithium cells.
You should also not directly solder to any lithium cell regardless if it is rechargeable or not. The heat needed can cause them to explode and if they don't explode, read the final cell voltage after direct soldering and you will find that your lithium cell may have lost a volt or so.
I've even seen lithium cells with solder tabs loose a volt or more when enough heat was needed to overcome a large ground plane area on a board with several layers of copper.
That's usually the result of using an iron of too low a wattage to properly heat the ground plane quickly though.
Batteries Plus used to spot weld solder tabs onto lithium coin cells so you could create custom voltage or capacity lithium packs.
They will no longer do such mainly for the explosion hazards even though spot welding a solder tab generates low heat for a very short time.
I'm not even sure they will spot weld solder tabs onto NiCD or NiMH coin cells any longer either but they will still spot weld solder tabs onto NiCD and NiMH AAA size cells or larger so they can create custom size packs for you. I don't think they will spot weld solder tabs onto any size Lithium cells at all today though.
They used to build up any size pack for you using your choice of battery chemistry but Lithium is out these days especially for coin or button cells.