Trying to do exactly this for a business in town, I just want to listen and map their DMR stuff. We'll see
Do you already have the DMR system created for them? If trying to use an OFT system, Discovery will only let you monitor one site (the single frequency) at a time.
For a prospective "new" DMR system (one not in the database), I may use one of two methods to get a starting point. I can program the channels conventionally, then let ProScan log activity on the frequencies to get an idea of which frequencies are used, color codes, and a sampling of the talkgroups. Or, program the frequencies into an OFT system, individual sites, and let ProScan collect the frequencies, color codes, and talkgroups that are in use.
For the x36HP & SDS series scanners, ProScan can give you a hint whether this is being used as a trunked system, or as DMR in a conventional mode.
Here in my dense metro area, the same Uhf frequency may be licensed to more than one entity, in some cases 6 to 8 licensees in my county at one time. The log helps look for clusters of talkgroups, on a frequency, that use the same color code. That comes into play when setting up a system, so that you can concentrate on one user, and not be distracted by others using the same frequency, but a different color code.