This is the best publicly available manual I could find (someone might find one better):
View and Download ZETRON Model 25 product manual online. Programmable Encoder. Model 25 media converter pdf manual download.
www.manualslib.com
Again, get the cable from Zetron unless you want to build it yourself (like $30-40 from them direct). Guide to build the cable here:
When you open PuTTy press SHIFT + P (uppercase "p") to start programming mode (make sure enable switch is "on" on the back of the unit).
There are a couple different models, like ones with display, one with quick keys only, etc. You can also buy expansion consoles. Basically you assign the quick keys (which can be buttons or just shortcut codes that are four-digit numbers starting with "0").
If you want, you can just do DTMF direct entry by assigned DTMF to a format number (for example, 3) then entering format number + DMTF code and hitting send. So an example would be (if you assigned 3 to be the DTMF format) to 3 + 1234 + Send, do send "1234" as DTMF.
Feel free to hit here with specific questions (just because I like other to be able to search and learn from the posts of others).