More than one talk group can be monitored with one RTL-SDR. But like most things with SDRs, it's a bit more complicated than that. If you want to use one RTL-SDR to capture talk groups on the system you reference, you will need a computer running Linux and OP25 software - I prefer the Boatbod version. If you are not well versed in computer technology, it will not be easy to set up and configure. If you don't mind paying $25 for the software, DSD+FL can be configured to run on a single SDR, and it uses the Windows OS. But again, not so easy to set up.