In the most basic of terms, I'm sure somebody will elaborate, radio signals bounce off a layer of the atmosphere called the ionosphere which is electronically charged from the Sun. They then bounce off the ground and bounce up to the ionosphere again and travel long distances as they skip along.
The sun has been minimized for a long time but we have entered solar cycle 25 and the ionosphere is more electronically charged by sunspot activity. You will find skip mostly on 11 m which is CB radio around 27 MHz or 10 m which is a ham band around 29 MHz.
You are most likely to encounter skip propagation on VHF low band than VHF high band or UHF which is very well explained above as tropospheric ducting.
That's about as basic as I can explain it but it is a very detailed scientific phenomena.