If by "Burnet", you mean Burnet County (and not the City), then there is no one single site that provides radio traffic for all of Burnet County.
As you have noted, Burnet and the entire Western Region is not Simulcast, so if a subscriber unit is not affiliated with the tower in question for that particular talkgroup, you will not hear traffic on that tower. Probably the best way to understand how traffic is "routed" on GATRRS WR is to understand that there are effectively 5 PSAPs (Burnet County (BU County North), City of Marble Falls (BU County South), Blanco, Llano and Lampasas). The talkgroups are organized around each PSAP and as such, the radio traffic generally follows this setup.
Using the 5 PSAPs, the following towers are genreally associated with each PSAP:
Burnet North: 71-Burnet; 72-Bertram; 70-Watson; (serving Burnet city/county, Bertram, NE Burnet VFD, East Lake Buchanan VFD, Cassie VFD)
Burnet South: 74-Marble Falls; 69-Singleton Bend (serving Marble Falls, Granite Shoals, Spicewood, Cottonwood Shores, Horseshoe Bay)
Blanco: 77-Round Mountain; 78-Johnson City; 79-Blanco
Llano: 76-Llano South; 75-Llano North
Lampasas: 68-Lampasas
A few notes/observations:
Site 71 is probably the primary tower for the city of Burnet and North Burnet county, you will hear the most traffic on it. 72 (Bertram) gets ~90% of the traffic but you will sometimes not hear any of the west side VFDs on it (East Lake and Cassie in particular). 70 (Watson) is only providing gap coverage for far NE Burnet County and Lamapsas so very little radio traffic. I think that site only has 2 frequencies associated with it.
Site 74 is the primary tower for Marble Falls and gets probably 99% of all traffic for those commmunities. 69 (Singleton Bend) is providing gap coverage for far SE Burnet County and some of Blanco County so the radio traffic can be limited.
Site 73 (Kingsland), as i understand it, is technically a Llano county tower--but is located on a hill in Burnet county (Lookout Mountain). This tower provides lake coverage for east Llano county but also provides gap coverage for western Burnet County for both Burnet and Marble Falls units. Cassie and Hoover Valley VFD units almost always connect to this tower, hence why you probably never hear them in Bertram. You will almost never hear Burnet units on Site 74 or Marble Falls units on Site 71, but Site 73 you can generally hear a significant amount of the radio traffic for 3 of the WR PSAPs (BU, MF and LL).
Site 64 (Stonewall) is in Gillepsie County and provides some gap coverage for Blanco county and occasionallly for Llano units when they respond to ERock. Very little radio traffic just like Watson. Same goes with Site 54-Mason.
For Blanco and Llano, there is no one single site that I would call a primary, but you generally hear all the traffic for that county on any of those sites and the occasional bleedover from units from neighboring counties.
Hope that helps answer your question.