A 40 watt iron will solder the center conductor nicely on the DXE "Next Generation" PL259s.
OTOH... with the CATV connector (known as a Type "F" connector) that you mention, the center conductor is the center pin.
They are easy to install and relatively cheap as is the RG6 coax. Actually, several of my ham antennas here are fed with RG6 using F connectors
(with appropriate adapters as necessary to mate with whatever). Don't worry too much about the 75 ohm thing as it really doesn't make a big difference in actual practice. But, this could open a whole another thread...
Don't worry too much about the 75 ohm thing
That's what I've never understood....IF I put a 75ohm terminator the cable reads 75 ohms....IF I take off the 75 and put on a 50 ohm terminator or dummy load....I read 50 ohms...I always thought it was how it was terminated.....guess I need to see it with a scope