The OP would be taking the earphone out of the scanner (low impedance) but feeding a high impedance audio input to the car stereo. That should work fine. The ground loop isolators can be a transformer or a simple capacitor to break the DC path and just let AC audio pass through. The point is to stop the shield of the audio cables from trying to bring the grounds at different points in the car tot the same potential by passing current through the shields.
It's a high impedance galvanic isolated transformer, usually two of them to handle stereo signals. It is not suited for low impedance loudspeakers. It helps with most noise problems from humm and generator whining.
/Ubbe