Is 145.8 the right frequency to listen to voice communications from the ISS? If not, what is the correct frequency? Thanks.
For the scheduled events, yes. Most ISS voice activity will be on the cross-band repeater, including random QSOs by ISS crewmembers. The repeater downlink is 437.800 MHz (+/- 10 kHz for Doppler - around 437.810 MHz at the start of a pass, ending around 437.790 MHz near the end), and the uplink is 145.990 MHz with 67.0 Hz tone.
I saw reports that an ISS crewmember was on the repeater this (Sunday, 12 October) morning before 11am PDT/1800 UTC. Crews have more free time on weekends, so you could hear a crewmember talking to hams some time...
73!