DTMF would not be considered a form of digital modulation. It's just audio tones: Dual Tone, Multi Frequency, modulated onto whatever carrier the radio is using.
And as nd5y linked to, completely legal to use on CB radio.
In fact, Radio Shack sold a CB frequency based paging system at one point that I ~think~ used DTMF.
Looked it up, 27.255MHz, which was CB channel 23, but also one of the remote control radio service frequencies.